catena-Poly[[diaqua(1,10-phenanthroline-κ2 N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ2 N 3:O 6]
نویسندگان
چکیده
In the title complex, [Ni(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is hexa-coordinated by one N and one O atom from two different 1H-benzimidazole-5,6-dicarboxyl-ate ligands, two N atoms from one 1,10-phenanthroline ligand and two water mol-ecules. The flexible 1H-benzimidazole-5,6-dicarboxyl-ate ligands link the Ni(II) centres, forming an infinite zigzag chain parallel to [001]. The crystal packing is governed by inter-molecular hydrogen-bonding inter-actions of the O-H⋯O, N-H⋯O and C-H⋯O types.
منابع مشابه
catena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ2 N 3:O 6] sesquihydrate}
In the title compound, {[Co(C9H4N2O4)(C12H8N2)(H2O)2]·1.5H2O} n , the Co(II) atom is hexa-coordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxyl-ate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water mol-ecules. The dihedral angle between the 1H-benzimidazole-5,6-dicarboxyl-ate and 1,10-phenanthroline ligands is 74.41 (4)°. ...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ4 O 2,O 2′:O 5,O 5′]
In the title coordination polymer, [Zn(C(6)H(2)O(5))(C(12)H(8)N(2))](n), an infinite chain is formed along [010] by linking the chelated {Zn(phen)} entities (phen is 1,10-phenanthroline) with two carboxyl-ate groups of the furan-2,5-dicarboxyl-ate ligand. The Zn(II) atom shows trigonal-prismatic coordination.
متن کاملcatena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4-hydroxy-3-sulfonatobenzoato-κ2 O 3:O 1] sesquihydrate]
The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion. It is also coordinated by two water mol-ecules in an overall octa-hedral environment. The dianion links adjacent metal atoms int...
متن کاملcatena-Poly[[[triaquaeuropium(III)]-μ-(1H-benzimidazole-5,6-dicarboxylato-κ2 O 5:O 6)-μ-(1H,3H-benzimidazol-3-ium-5,6-dicarboxylato-κ3 O 5:O 6,O 6′)] dihydrate]
In the title one-dimensional coordination polymer, {[Eu(C(9)H(4)N(2)O(4))(C(9)H(5)N(2)O(4))(H(2)O)(3)]·2H(2)O}(n), one of the 1H-benzimidazole-5,6-dicarboxyl-ate (Hbdc) ligands is protonated at the imidazole group (H(2)bdc). The Eu(III) ion is eight-coordinated by two O atoms from two Hbdc ligands, three O atoms from two H(2)bdc ligands and three water mol-ecules, showing a distorted square-ant...
متن کاملPoly[diaqua(μ4-2,5-dicarboxybenzene-1,4-dicarboxylato-κ4 O 1:O 2:O 4:O 5)(μ2-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2 O 1:O 4)bis(1,10-phenanthroline-κ2 N,N′)dimanganese(II)]
In the title compound, [Mn(2)(C(10)H(4)O(8))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Mn(2+) ion has a slightly distorted octa-hedral N(2)O(4) coordination geometry being coordinated by one aqua O atom, two N atoms of the chelating 1,10-phenanthroline ligand and three carboxyl O atoms from three 2,5-dicarb-oxy-benzene-1,4-dicarboxyl-ate (H(2)btec(2-)) ligands. The H(2)btec(2-) anion exhibits two...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009